Yes, with Android Wear for iOS, you have the ability to sync the LG Watch Urbane 2nd Edition LTE smart watch. This provides call syncing capability; however, with messaging, syncing is limited. AT&T Messages Backup & Sync (AMBS) does not sync your text messages with your iPhone nor can you access iMessages from the smart watch.
For the best possible experience while using the NumberSync for wearables service with iPhone, you’ll need to turn off iMessage® in order to receive all text messages on the smart watch. On your iPhone, go to Settings, Messages, iMessage and select OFF. When not utilizing NumberSync for wearables, you can choose to turn iMessage back on.